臭氧及臭氧类高级氧化技术降解甲基对硫磷的效能          下载免费PDF全文

林存旺  许珊珊  项丰云  章小芳 《海洋开发与管理》2018,35(9):94-99

文章研究了臭氧及臭氧类高级氧化技术(AOPs-O3)在不同pH条件下降解甲基对硫磷(MP)的效能。结果表明,在pH 3~10的条件下(反应过程控制pH),单独臭氧化5min即可完全降解MP,但不同pH下化学耗氧量(COD)和有机磷的释放率差异明显。在pH为3.3,7.5和9.4的条件下单独臭氧30min后COD的去除率分别为55.17%,89.64%和93.10%,有机磷的释放率分别为16.33%,95.00%和99.99%。考虑酸性条件下可以规避碳酸盐的负面影响(特别是高浓度废水),利用O3/H2O2/Ti(IV)在pH 3.3条件下处理MP溶液,COD去除率和有机磷释放率分别达到89.64%和81.57%。相对法计算求得MP与O3和羟基自由基(·OH)的速率常数分别为31.98L·(mol·s)-1和7.488×109 L·(mol·s)-1。活性污泥法的测试结果表明,MP经O3/Ti(IV)/H2O2(pH=3.3)和O3(pH=9.4)可提升含MP废水的可生化性,但与培养液体系相比仍具有一定的毒性。  相似文献   

Intensity of in‐lake processes in floodplain lakes within the Bug River zone of fluvial activity          下载免费PDF全文

Jarosław Dawidek  Beata Ferencz 《水文研究》2014,28(24):5965-5971

The paper presents a new approach to calculating the erosion and deposition values of floodplain lake basins, the erosion–deposition index (EDI). The EDI is a sum of the basin geometry indices (BGIs), which can be calculated for a separate cross section of the lake. The distribution of processes within the basin was investigated in two selected floodplain lakes with the use of BGIs. Field research was carried out in the Bug River valley from 1 November 2006 to 31 October 2011. The highest erosion was observed in the lakes located close to the parent river. Deposition processes were observed in lakes with high inflow of groundwater. The results showed that EDI values of 48 out of the 71 floodplain lakes ranged from ?0.2 to 0.2. Spatial distribution of erosion and deposition processes within the lake basins resulted from a velocity of water inflowing or flowing through the basin. This was observed especially in contrafluent–confluent lake. Inflow of rivers water via upstream crevasse occurred later than via downstream one, but energy of flowing water was higher, which favoured erosion of this part of the lake basin. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Geography Deserts: State and Regional Variation in the Formal Opportunity to Learn Geography in the United States, 2005–2015     

Mark C. Jones  Marcos Luna 《The Journal of geography》2019,118(2):88-100

The formal opportunity to learn geography in the United States is unevenly distributed across space, creating possible geography deserts. Data on the number of exams taken in Advanced Placement Human Geography (APHG) and bachelor’s degrees earned in geography are mapped at the state and regional scales. Normalized rates are ranked and grouped into quintiles. For APHG exams, states in the southeastern region of the United States are in the uppermost quintiles while states in the northeastern region are in the lowermost quintiles. The pattern for bachelor’s degrees in geography is somewhat the spatial inverse of that for APHG.  相似文献   

考虑尺寸效应的近海桥梁天然橡胶隔震支座力学性能老化时变规律研究          下载免费PDF全文

李艳敏  马玉宏  赵桂峰 《世界地震工程》2020,(4):169-177

目前天然橡胶支座（NRB）的性能研究大多未考虑尺寸效应，在前期开展的近海桥梁隔震支座和材料老化时变规律研究的基础上，同时考虑支座直径尺寸变化和老化作用时间的影响对NRB的性能进行研究。首先采用ABAQUS有限元软件对不同直径尺寸NRB的性能进行分析，得到了NRB性能随直径尺寸的变化规律；然后结合前期老化作用对NRB及其橡胶材料性能时变规律的影响研究成果，分析了直径尺寸及老化作用时间共同作用下，NRB性能的变化规律，并通过ABAQUS有限元分析，验证了该变化规律的准确性。结果表明:NRB的水平刚度和竖向刚度均随其直径尺寸的增大呈正比例增大趋势；NRB水平刚度比和竖向刚度比均随老化作用时间的增长呈线性增大趋势；且直径为150mm的NRB在实际环境老化60a后，其水平刚度和竖向刚度的增长幅度分别为:30.8%和16.41%，由此可见老化作用时间对NRB水平刚度的影响较显著，对其竖向刚度的影响较小。研究内容可为隔震桥梁结构中支座缩尺模型试验的相关设计提供参考，并为将实验室缩尺橡胶隔震支座的相关成果较好地应用于实际工程计算及设计中提供依据。  相似文献   

基于高斯烟羽模型的船舶尾气扩散研究     

付金宇  李颖 《海洋通报》2018,(2):235-240

为有效对港区大气污染进行治理、分析船舶尾气,本文详细介绍了一种基于高斯烟羽模型,通过MATLAB模拟仿真模型,其包括实验仿真过程、技术原理及理论模型对船舶尾气扩散进行的研究。该模型是在传统的高斯烟羽模型的基础上,通过对实源像源进行加权选择输入参数;通过矢量合成确定了气体扩散的方向,利用合成后的"风速"进行计算仿真,有效模拟了船舶尾气在港区或者海洋环境中的气体扩散模型。其模型简单且可以有效模拟船舶尾气扩散。并且进一步对后续模型的精确优化进行分析。  相似文献   

应急演练中基于G-R关系的主余型地震余震震级模拟     

王青平  王辉山  肖健  林岩钊  周施文  张树君 《震灾防御技术》2018,13(1):187-194

在现有的日常地震演练过程中，与应急救援密切相关的地震余震信息产品较为缺乏，直接影响发震构造的判断以及影响场修正等关键环节。本文从计算机系统提供的均匀分布随机数出发，运用反函数法模拟生成余震序列，并进行系统检验，证实该方法产生的余震序列满足G-R频次关系。模拟生成的余震震级数据既有助于增强地震应急救援演练的现实性，也有助于丰富地震应急宣传产品，提升地震部门的履职能力。  相似文献   

Effects of the geometry of two‐dimensional fractures on their hydraulic aperture and on the validity of the local cubic law          下载免费PDF全文

Ahmad Hajjar  Luc Scholtès  Constantin Oltéan  Michel Antoine Buès 《水文研究》2018,32(16):2510-2525

Flow through rough fractures is investigated numerically in order to assess the validity of the local cubic law for different fracture geometries. Two‐dimensional channels with sinusoidal walls having different geometrical properties defined by the aperture, the amplitude, and the wavelength of the walls' corrugations, the corrugations asymmetry, and the phase shift between the two walls are considered to represent different fracture geometries. First, it is analytically shown that the hydraulic aperture clearly deviates from the mean aperture when the walls' roughness, the phase shift, and/or the asymmetry between the fracture walls are relatively high. The continuity and the Navier–Stokes equations are then solved by means of the finite element method and the numerical solutions compared to the theoretical predictions of the local cubic law. Reynolds numbers ranging from 0.066 to 66.66 are investigated so as to focus more particularly on the effect of flow inertial effects on the validity of the local cubic law. For low Reynolds number, typically less than 15, the local cubic law properly describes the fracture flow, especially when the fracture walls have small corrugation amplitudes. For Reynolds numbers higher than 15, the local cubic law is valid under the conditions that the fracture presents a low aspect ratio, small corrugation amplitudes, and a moderate phase lag between its walls.  相似文献   

中国北极科技外交论析     

张佳佳  王晨光 《世界地理研究》2020,29(1):63-70

鉴于北极特殊的地理位置和自然环境，北极科技外交往往是各国参与北极事务的起点和实现北极利益的先导。中国也概不能外，北极科技外交对保障北极科研装备、提高北极认识水平和促进北极资源开发等都具有重要意义。回溯中国参与北极事务的历程，北极科技外交是其中的主要线索和核心内容，现已取得了一些成绩。但作为域外国家和发展中国家，中国北极科技外交还面临着缺乏顶层设计、政策和资金支持不足以及若干国际因素的掣肘。对此，中国应通过充分发挥政府的主导作用、强化和完善运行机制、扩展北极科技外交的广度和深度等加以改进。  相似文献   

农户的非农就业如何影响中国的土地流转?   总被引：1，自引：0，他引：1  

王佳月  辛良杰  王亚辉 《地理学报(英文版)》2020,30(3):378-400

To clarify the impact of non-agricultural employment on rural land circulation in China,we built logit models using the Chinese Household Income Project 2013 dataset,which includes 18,948 household samples over 15 provinces,126 cities and 234 counties of China in 2013.We use the proportion of non-agricultural income,the proportion of non-agricultural laborers and non-agricultural fixed operating assets to reflect the degree of the households’dependence on agriculture,the degree of the households’laborers committed to non-agricultural employment and the stability of non-agricultural employment,respectively.The results show that the stability of non-agricultural employment is an important reason for farmers to transfer out their land,and an increase in non-agricultural income is the fundamental reason.The proportion of non-agricultural assets has the greatest impact on the decision to transfer land,followed by the proportion of non-agricultural income.Per unit increase in the non-agricultural income ratio has a stronger effect on the transfer-out decision than it does on the transfer-in decision,which is a 0.09 increase of the probability of transfer-out the land and a 0.07 decrease of the probability of transfer-in the land.In terms of regional differences,when considering the impact of non-agricultural employment on the land transfer-out decision,the impacts of non-agricultural income and labor force are the greatest in the Central region.The impact of non-agricultural assets is the greatest in the Eastern region.For the Eastern region,the decision to transfer out land is mainly affected by non-agricultural assets and the non-agricultural labor force,and the decision to transfer in land is mainly affected by non-agricultural assets.In the Central and Western regions,the decision to transfer out land is mainly affected by non-agricultural assets,non-agricultural income and the non-agricultural labor force,in that order.The decision to transfer in land in the Central region is not significantly affected by non-agricultural employment.The decision to transfer in land in the Western region is mainly affected by non-agricultural assets,non-agricultural labor force and non-agricultural income,in that order.We note that non-agricultural assets have a prominent impact on land transfer,which shows that the stability of non-agricultural employment has an important impact on land transfer decision-making.Vocational training for rural labor forces may be an effective means to promote stable non-agricultural employment and simultaneously facilitate rural land circulation,especially in Central and Western China.  相似文献   

Coordinative similitude law considering fluid‐structure interaction for underwater shaking table tests     

Zhong‐Xian Li  Kun Wu  Yundong Shi  Ning Li  Yang Ding 《地震工程与结构动力学》2018,47(11):2315-2332

Generally, when a model is made of the same material as the prototype in shaking table tests, the equivalent material density of the scaled model is greater than that of the prototype because mass is added to the model to satisfy similitude criteria. When the water environment is modeled in underwater shaking table tests, however, it is difficult to change the density of water. The differences in the density similitude ratios of specimen materials and water can affect the similitude ratios of the hydrodynamic and wave forces with those of other forces. To solve this problem, a coordinative similitude law is proposed for underwater shaking table tests by adjusting the width of the upstream face of the model or the wave height in the model test to match the similitude ratios of hydrodynamic and wave forces with those of other forces. The designs of the similitude relations were investigated for earthquake excitation, wave excitation, and combined earthquake and wave excitation conditions. Series of numerical simulations and underwater shaking table tests were performed to validate the proposed coordinative similitude law through a comparison of coordinative model and conventional model designed based on the coordinative similitude law and traditional artificial mass simulation, respectively. The results show that the relative error was less than 10% for the coordinative model, whereas it reached 80% for the conventional model. The coordinative similitude law can better reproduce the dynamic responses of the prototype, and thus, this similitude law can be used in underwater shaking table tests.  相似文献